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DIFFERENT TYPES OF WINDOW FILM.
    All window films start with the film, of course, which is always polyester, 2 to 7 mils thick.
    Quite often, several thin layers of film are bonded together. One side is coated with
    either a pressure-sensitive or water-activated adhesive. The exposed surfaces of most
    films are also treated with a hard, scratch-resistant coating.

    To filter out ultraviolet radiation, chemical UV blockers (cyclic imino esters) are
    incorporated. If the film's purpose is to provide only UV protection and shatter
    resistance, no other materials need to be added.
    DYED FILM

    Single-Ply Dyed Window Film with Standard Scratch Resistant Hard
    coat

    From there, three separate technologies are applied to achieve
    different performance characteristics. The first is simply a dye, which
    absorbs heat. Because most films are applied to the inside surfaces
    of windows, it's easy to imagine that the absorbed heat would
    disperse indoors. In fact, the heat rejected by the film is stored largely
    in the glass, and is drawn away by external air movement. A tiny
    percentage does bleed inward, but because the average speed of
    external air movement is so much greater-the daily average is 15 mph,
    versus 1/2 mph indoors-the ratio is 30:1 or better in favor of outdoor
    heat dissipation. Because double-glazed windows don't allow air
    movement between panes, interior-dyed films should not be used on
    thermal glass.

    The other two processes, called deposition technology (vacuum
    coating/metallizing) and sputtering technology (advanced metallizing),
    deposit a layer of metallic particles on the film, giving it a reflective
    coating. In each case, a second layer of film protects the coating.
    Metallized films reject heat by reflecting it before it can be transferred
    through the glass.
    DEPOSITED FILM

    In deposition technology, the film is drawn through a tank containing
    metal ingots-usually aluminum or nickel-chrome, and occasionally
    copper. A vacuum is created by reducing the pressure in the tank,
    which is then flooded with argon gas and the ingots are heated. The
    heat causes the metal to give up particles that migrate to the film's
    surface. The density of the metal deposition is controlled by the speed
    of the film through the chamber.

    While deposition technology works well and is relatively inexpensive, it
    has its limits. To be effective, the metallized coating must be fairly
    thick, as the particles are comparatively large. What this means at a
    practical level is that it produces a darker, more highly mirrored
    surface. And second, the list of metals that can be deposited evenly is
    fairly short, which means fewer product options.
    SPUTTERED FILM

    Two-Ply Metallized Window Film with Metallized and UV Treated Film
    Layers

    Sputtering technology is more complicated. Sputtering is also done in
    a vacuum chamber, but the metallizing is achieved at the atomic level.
    In brief, electromagnetic fields direct streams of ions from a
    chemically inert gas (usually argon) toward the metal. This ion
    bombardment, which is often described as "atomic billiards," causes
    groups of atoms to dislodge in small bursts and scatter uniformly
    across the film.

    The practical benefits of sputtering are that 25 to 30 different metals
    can be used and the metallized coating is much lighter. It's possible to
    sputter metal in a layer one-hundredth the thickness of a human hair.
    Different metals are chosen to subtract specific bands of radiation
    from the solar spectrum. The result is a highly reflective layer with very
    little mirror effect, heat absorption or color shift. Because sputtering is
    more expensive, these films occupy the high end of the price range.
    Metallic films control radiation through reflectivity. Simplified film
    consists of polyester layers, metallic coating, adhesive and scratch-
    resistant coatings.

    While the performance characteristics of dyed and metallic films are
    generally distinct, there is some overlap. Heat-absorbing dyed films
    are somewhat reflective, and metallic films do absorb some heat
    because of the mass and color of the metals involved.
    HYBRID FILM

    To further complicate the issue, many films contain both dyes and
    reflective metals. By combining dyes and metals, the negative effects
    of each can be reduced without sacrificing performance. A good
    example is gray dye and titanium coating. If used alone, dye would
    darken the film significantly, while the titanium would produce a highly
    mirrored surface. When paired, less of each can be used, resulting in
    a film that is relatively bright and non reflective.

    This point is significant, if only because it quells the notion that the
    darkest films reject the most heat. In most cases, dark films are
    chosen because they offer greater privacy.